Journal Article

PreJuSER-22364

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Water Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11

Zhu, G. ; Geletii, Y. V. ; Kögerler, P.FZJ* ; Schilder, H. ; Song, J. ; Lense, S. ; Zhao, C. ; Hardcastle, K. I. ; Musaev, D. G. ; Hill, C. L.

2012
Soc. London

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Please use a persistent id in citations: http://hdl.handle.net/2128/7530  doi:10.1039/C1DT11211B

Abstract: A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.

Keyword(s): J

Note: The present research is supported by grant DE-FG02-03ER15461 from the U.S. Department of Energy. The authors gratefully acknowledge NSF MRI-R2 grant (CHE-0958205) and the use of the resources of the Cherry Emerson Center for Scientific Computation.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2012

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Database coverage:
; ; Allianz-Lizenz / DFG ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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