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000022364 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000022364 1001_ $$0P:(DE-HGF)0$$aZhu, G.$$b0
000022364 245__ $$aWater Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11
000022364 260__ $$aLondon$$bSoc.$$c2012
000022364 300__ $$a2084 - 2090
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000022364 440_0 $$015301$$aDalton Transactions$$v41$$x1477-9226$$y7
000022364 500__ $$3POF3_Assignment on 2016-02-29
000022364 500__ $$aThe present research is supported by grant DE-FG02-03ER15461 from the U.S. Department of Energy. The authors gratefully acknowledge NSF MRI-R2 grant (CHE-0958205) and the use of the resources of the Cherry Emerson Center for Scientific Computation.
000022364 520__ $$aA new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.
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000022364 7001_ $$0P:(DE-HGF)0$$aSchilder, H.$$b3
000022364 7001_ $$0P:(DE-HGF)0$$aSong, J.$$b4
000022364 7001_ $$0P:(DE-HGF)0$$aLense, S.$$b5
000022364 7001_ $$0P:(DE-HGF)0$$aZhao, C.$$b6
000022364 7001_ $$0P:(DE-HGF)0$$aHardcastle, K.I.$$b7
000022364 7001_ $$0P:(DE-HGF)0$$aMusaev, D.G.$$b8
000022364 7001_ $$0P:(DE-HGF)0$$aHill, C.L.$$b9
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