TY  - JOUR
AU  - Zhu, G.
AU  - Geletii, Y.V.
AU  - Kögerler, P.
AU  - Schilder, H.
AU  - Song, J.
AU  - Lense, S.
AU  - Zhao, C.
AU  - Hardcastle, K.I.
AU  - Musaev, D.G.
AU  - Hill, C.L.
TI  - Water Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11
JO  - Dalton transactions
VL  - 41
SN  - 1477-9226
CY  - London
PB  - Soc.
M1  - PreJuSER-22364
SP  - 2084 - 2090
PY  - 2012
N1  - The present research is supported by grant DE-FG02-03ER15461 from the U.S. Department of Energy. The authors gratefully acknowledge NSF MRI-R2 grant (CHE-0958205) and the use of the resources of the Cherry Emerson Center for Scientific Computation.
AB  - A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
C6  - pmid:22186630
UR  - <Go to ISI:>//WOS:000299505100020
DO  - DOI:10.1039/c1dt11211b
UR  - https://juser.fz-juelich.de/record/22364
ER  -