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245 _ _ |a A Polyoxometalate-Based Single-Molecule Magnet with an S = 21/2 Ground State
260 _ _ |a Cambridge
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|c 2012
300 _ _ |a 1218 - 1220
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|y 9
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a We are grateful to Dr Gordon Miller for allowing us access to X-ray facilities. Ames Laboratory is operated for the U.S. Department of Energy by Iowa State University under Contract No. DE-AC02-07CH11358.
520 _ _ |a Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(III)(3)Mn(IV)O(4)] core into a centrosymmetric [Mn(III)(6)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.
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856 7 _ |u http://dx.doi.org/10.1039/C1CC15520B
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|y Published under German "Allianz" Licensing conditions on 2011-11-18. Available in OpenAccess from 2012-11-18
|z Published final document.
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