Journal Article PreJuSER-22481

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A Polyoxometalate-Based Single-Molecule Magnet with an S = 21/2 Ground State

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2012
Soc. Cambridge

Chemical communications 48, 1218 - 1220 () [10.1039/c1cc15520b]

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Abstract: Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(III)(3)Mn(IV)O(4)] core into a centrosymmetric [Mn(III)(6)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.

Keyword(s): J


Note: We are grateful to Dr Gordon Miller for allowing us access to X-ray facilities. Ames Laboratory is operated for the U.S. Department of Energy by Iowa State University under Contract No. DE-AC02-07CH11358.

Contributing Institute(s):
  1. Elektronische Eigenschaften (PGI-6)
Research Program(s):
  1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2012
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Medline ; OpenAccess by Allianz-OA ; Allianz-Lizenz / DFG ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2012-11-13, last modified 2018-02-10


Published under German "Allianz" Licensing conditions on 2011-11-18. Available in OpenAccess from 2012-11-18:
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