TY - JOUR AU - Díaz Álvarez, Adrian AU - Xu, Tao AU - Tütüncüoglu, Gözde AU - Demonchaux, Thomas AU - Nys, Jean-Philippe AU - Berthe, Maxime AU - Matteini, Federico AU - Potts, Heidi A. AU - Troadec, David AU - Patriarche, Gilles AU - Lampin, Jean-François AU - Coinon, Christophe AU - Fontcuberta i Morral, Anna AU - Dunin-Borkowski, Rafal AU - Ebert, Philipp AU - Grandidier, Bruno TI - Nonstoichiometric Low-Temperature Grown GaAs Nanowires JO - Nano letters VL - 15 IS - 10 SN - 1530-6992 CY - Washington, DC PB - ACS Publ. M1 - FZJ-2015-06017 SP - 6440–6445 PY - 2015 AB - The structural and electronic properties of nonstoichiometric low-temperature grown GaAs nanowire shells have been investigated with scanning tunneling microscopy and spectroscopy, pump–probe reflectivity, and cathodoluminescence measurements. The growth of nonstoichiometric GaAs shells is achieved through the formation of As antisite defects, and to a lower extent, after annealing, As precipitates. Because of the high density of atomic steps on the nanowire sidewalls, the Fermi level is pinned midgap, causing the ionization of the subsurface antisites and the formation of depleted regions around the As precipitates. Controlling their incorporation offers a way to obtain unique electronic and optical properties that depart from the ones found in conventional GaAs nanowires. LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000363003100023 DO - DOI:10.1021/acs.nanolett.5b01802 UR - https://juser.fz-juelich.de/record/255938 ER -