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@ARTICLE{Frielinghaus:256119,
author = {Frielinghaus, R. and Besson, C. and Houben, L. and
Saelhoff, A.-K. and Schneider, C. M. and Meyer, Carola},
title = {{C}ontrolled covalent binding of antiferromagnetic
tetramanganese complexes to carbon nanotubes},
journal = {RSC Advances},
volume = {5},
number = {102},
issn = {2046-2069},
address = {London},
publisher = {RSC Publishing},
reportid = {FZJ-2015-06128},
pages = {84119 - 84124},
year = {2015},
abstract = {We report on the covalent functionalization of carbon
nanotubes with tetramanganese complexes. The process is
based on ligand exchange with carboxylic groups on the
preliminarily oxidized tubes and does not fundamentally
affect the antiferromagnetic coupling between the manganese
ions of the complex. We present detailed analysis of the
oxidation process and demonstrate that the degree of
functionalization directly relates to the density of
carboxylic groups. The coverage of a carbon nanotube can be
decreased enough to enable fabrication of electronic devices
incorporating an individual molecule.},
cin = {PGI-6},
ddc = {540},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000362752400070},
doi = {10.1039/C5RA14983E},
url = {https://juser.fz-juelich.de/record/256119},
}