Journal Article

FZJ-2015-06128

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Controlled covalent binding of antiferromagnetic tetramanganese complexes to carbon nanotubes

Frielinghaus, R. ; Besson, C.FZJ* ; Houben, L.FZJ* ; Saelhoff, A.-K. ; Schneider, C. M.FZJ* ; Meyer, C. (Corresponding author)FZJ*

2015
RSC Publishing London

This record in other databases:  

Please use a persistent id in citations: doi:10.1039/C5RA14983E

Abstract: We report on the covalent functionalization of carbon nanotubes with tetramanganese complexes. The process is based on ligand exchange with carboxylic groups on the preliminarily oxidized tubes and does not fundamentally affect the antiferromagnetic coupling between the manganese ions of the complex. We present detailed analysis of the oxidation process and demonstrate that the degree of functionalization directly relates to the density of carboxylic groups. The coverage of a carbon nanotube can be decreased enough to enable fabrication of electronic devices incorporating an individual molecule.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 522 - Controlling Spin-Based Phenomena (POF3-522) (POF3-522)

Appears in the scientific report 2015

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Database coverage:
; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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