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000000259 084__ $$2WoS$$aChemistry, Applied
000000259 084__ $$2WoS$$aChemistry, Physical
000000259 084__ $$2WoS$$aNanoscience & Nanotechnology
000000259 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000000259 1001_ $$0P:(DE-Juel1)VDB75796$$avan der Donk, G.$$b0$$uFZJ
000000259 245__ $$aFormation of clathrasil layers by secondary growth of DOH-type nuclei for gas separation applications
000000259 260__ $$aAmsterdam [u.a.]$$bElsevier$$c2008
000000259 300__ $$a3 - 10
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000000259 440_0 $$011881$$aMicroporous and Mesoporous Materials$$v115$$x1387-1811
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000000259 520__ $$aDoclecasil 1 H (D1H) possessing the zeolite framework type DOH is one of the all-silica zeolites and therefore offers high chemical, thermal and hydrothermal stability. D1H is a 6-ring clathrasil with small pore apertures of about 3 A and may be able to selectively transport hydrogen or helium while rejecting other gasses such as CO2. These properties make D1H an interesting microporous membrane material for pre-combustion applications. Moreover, it has been shown that D1H crystals can be prepared practically structure directing agent-free.Prior to the attempt to prepare complete layers of D1H crystals, the general crystallisation behaviour of D1H was investigated. To obtain optimal crystallisation conditions a large number of synthesis experiments were performed aiming, in particular, at the preparation of pure material consisting of small and very thin crystals with a reduced number of organic molecules occupying the cage-like voids of the structure. The syntheses were performed in the system aminoadamantane/silica/ethylenediamine or ammonia/water and by systematically varying synthesis parameters like temperature, gel composition, aging of the synthesis mixture, seeding and the type of agitation during the synthesis run. In some additional runs aminoadamantane was replaced by other structure directing agents.Moreover, the removal the organics filling the zeolite cages was studied by different approaches, including calcination at atmospheric pressure and by applying high pressure cycling and calcination of ball milled crystals. The obtained materials were then characterized by powder XRD, SEM, thermal analysis, chemical analysis and optical microscopy. Knowing favourable synthesis conditions, D1H layers have been prepared on a alpha-Al2O3 support by using secondary growth of small D1H nuclei. (C) 2008 Elsevier Inc. All rights reserved.
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000000259 65320 $$2Author$$aclathrasil
000000259 65320 $$2Author$$aD1H
000000259 65320 $$2Author$$aDOH
000000259 65320 $$2Author$$adodecasil 1H
000000259 65320 $$2Author$$aDDR
000000259 65320 $$2Author$$asecondary growth
000000259 65320 $$2Author$$azeolite
000000259 65320 $$2Author$$azeolitic layers
000000259 65320 $$2Author$$azeolite membranes
000000259 7001_ $$0P:(DE-HGF)0$$aSerra, J. M.$$b1
000000259 7001_ $$0P:(DE-Juel1)VDB77815$$aMarler, B.$$b2$$uFZJ
000000259 7001_ $$0P:(DE-Juel1)129637$$aMeulenberg, W. A.$$b3$$uFZJ
000000259 7001_ $$0P:(DE-HGF)0$$aGies, H.$$b4
000000259 773__ $$0PERI:(DE-600)2012505-7$$a10.1016/j.micromeso.2007.11.052$$gVol. 115, p. 3 - 10$$p3 - 10$$q115<3 - 10$$tMicroporous and mesoporous materials$$v115$$x1387-1811$$y2008
000000259 8567_ $$uhttp://dx.doi.org/10.1016/j.micromeso.2007.11.052
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