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@ARTICLE{Radulescu:276170,
author = {Radulescu, Aurel and Goerigk, Günter and Fetters, Lewis
and Richter, Dieter},
title = {{M}orphology of crystalline–amorphous olefin block
copolymers in solution characterized by small-angle neutron
scattering and microscopy},
journal = {Journal of applied crystallography},
volume = {48},
number = {6},
issn = {1600-5767},
address = {Copenhagen},
publisher = {Munksgaard},
reportid = {FZJ-2015-06637},
pages = {1860-1869},
year = {2015},
abstract = {The single-chain properties and self-assembly behavior in
dilute solution of olefin block copolymers obtained by
chain-shuttling technology and consisting of alternating
crystallizable and amorphous ethylene/1-octene blocks were
investigated by pinhole and focusing small-angle neutron
scattering techniques, optical microscopy in bright-field
and crossed-polarizer modes, and differential scanning
calorimetry. The complex hydrocarbon soluble (precipitant
free) macro-aggregates formed with decreasing temperature
are characterized by spherulitic textures. The spherulites
yield, on one hand, a morphology that depends on the chain
structure properties and, on the other hand, multiple
structural levels with a hierarchical organization that
ranges from 10 Å up to tens of micrometres. This morphology
displays peculiarities dictated by the polydisperse
character of these materials.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {144 - Controlling Collective States (POF3-144) / 6213 -
Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G15 - FRM II / MLZ (POF3-6G15) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-6213 /
G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)KWS3-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000365774800031},
pubmed = {pmid:26664344},
doi = {10.1107/S1600576715019226},
url = {https://juser.fz-juelich.de/record/276170},
}