TY - JOUR
AU - Chyrkin, Anton
AU - Pillai, Rishi
AU - Ackermann, H.
AU - Hattendorf, H.
AU - Richter, S.
AU - Nowak, Wojciech
AU - Grüner, Daniel
AU - Quadakkers, Willem J.
TI - Modeling Carbid Dissolution in Alloy 602 CA During High Temperature Oxidation
JO - Corrosion science
VL - 96
SN - 0010-938X
CY - Amsterdam [u.a.]
PB - Elsevier Science
M1 - FZJ-2015-07472
SP - 32-41
PY - 2015
AB - The high-temperature oxidation resistance of the carbide strengthened nickel-base alloy 602 CA is provided by the formation of a protective outer Cr2O3 scale accompanied by internal precipitation of alumina and dissolution of Cr-rich carbides. The carbide free zone formation has been discussed in the literature to be a consequence of either chromium depletion or alloy decarburization.A new dissolution mechanism is proposed in this paper. Carbide dissolution in alloy 602 CA exposed to oxidizing atmospheres at 1100 °C was studied. The alloy microstructure was characterized by means of SEM/EDX/EPMA and GDOES. The experimental observations were substantiated by CALPHAD based computations.
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000356121500005
DO - DOI:10.1016/j.corsci.2015.03.019
UR - https://juser.fz-juelich.de/record/279588
ER -