| Home > Publications database > Modeling Carbid Dissolution in Alloy 602 CA During High Temperature Oxidation |
| Journal Article | FZJ-2015-07472 |
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2015
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.corsci.2015.03.019
Abstract: The high-temperature oxidation resistance of the carbide strengthened nickel-base alloy 602 CA is provided by the formation of a protective outer Cr2O3 scale accompanied by internal precipitation of alumina and dissolution of Cr-rich carbides. The carbide free zone formation has been discussed in the literature to be a consequence of either chromium depletion or alloy decarburization.A new dissolution mechanism is proposed in this paper. Carbide dissolution in alloy 602 CA exposed to oxidizing atmospheres at 1100 °C was studied. The alloy microstructure was characterized by means of SEM/EDX/EPMA and GDOES. The experimental observations were substantiated by CALPHAD based computations.
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