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@ARTICLE{Kang:280392,
author = {Kang, Kyongok},
title = {{C}harged {C}olloidal {R}ods {O}ut of {E}quilibrium},
journal = {Advances in Chemical Engineering and Science},
volume = {05},
number = {01},
issn = {2160-0406},
address = {Irvine, Calif.},
publisher = {Scientific Research Publ.},
reportid = {FZJ-2016-00169},
pages = {23 - 32},
year = {2015},
abstract = {This article is a comprehensive overview of the ongoing
research of the author on charged colloid- al rods out of
equilibrium, under external electric fields and at high
concentrations around the glass transition. The suspensions
of fd-virus particles are used as a model system for charged
col- loidal rods, which exhibit several disorder-order (and
liquid-crystalline) phase transitions. When a low AC
electric field is applied to suspensions in
isotropic-nematic coexistence concentration, with
frequencies that are sufficiently low to polarize the
electric double layer and the layer of condensed ions,
various phases/states are induced: a chiral nematic, a
dynamical state where ne- matic domains persistently melt
and form, and a uniform homeotropic phase. A point in the
field-amplitude versus frequency diagram, where various
transitions lines meet, can be identified as a
non-equilibrium critical point. Without an electric field,
at high concentrations of charged fd-rods, various
self-assembled orientation textures are found beyond the
isotropic-nematic coex- istence regions, and a glass
transition is observed on approach and within the glass
state that are probed. The presented system exhibits
transient behaviors of repulsive glasses and slow dynamics
out of equilibrium.},
cin = {ICS-3},
ddc = {660},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551)},
pid = {G:(DE-HGF)POF3-551},
typ = {PUB:(DE-HGF)16},
doi = {10.4236/aces.2015.51003},
url = {https://juser.fz-juelich.de/record/280392},
}