Journal Article

FZJ-2016-00739

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Asymmetric Bio- and Organocatalytic Cascade Reaction - Laccase and Secondary Amine-Catalyzed α-Arylation of Aldehydes

Suljić, S. ; Pietruszka, J. (Corresponding author)FZJ* ; Worgull, D. (Corresponding author)

2015
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1002/adsc.201500183

Abstract: An asymmetric bio- and organocatalytic cascade one-pot reaction for the α-arylation of aldehydes is presented. 1,4-Dihydroxybenzene and its derivatives are oxidized to quinones by laccase and aerial oxygen. This catalytic process has been efficiently coupled to asymmetric enamine organocatalysis, affording 3-substituted 2,3-dihydrobenzofuran-2,5-diols in moderate to good yield and moderate to excellent enantioselectivity.

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Contributing Institute(s):

1. Institut für Bioorganische Chemie (HHUD) (IBOC)
2. Biotechnologie (IBG-1)

Research Program(s):

1. 581 - Biotechnology (POF3-581) (POF3-581)

Appears in the scientific report 2015

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Database coverage:
; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; No Authors Fulltext ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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