Home > Publications database > Total Synthesis of Solandelactones A and B |
Journal Article | FZJ-2016-00745 |
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2015
Wiley-VCH Verl.
Weinheim
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Please use a persistent id in citations: doi:10.1002/ejoc.201500700
Abstract: The total synthesis of solandelactones A and B is presented. The eastern cyclopropyl moiety was prepared following an exceptionally short chemoenzymatic approach whereas enantioselective synthesis of the western side-chain relied on the application of diastereomerically pure allyl boronates. The natural products solandelactones A and B were isolated in good overall yields following convergence of each eastern and western element by application of the Nozaki–Hiyama–Kishi reaction.
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