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@ARTICLE{Kieslich:281119,
author = {Kieslich, Gregor and Cerretti, Giacomo and Veremchuk, Igor
and Panthöfer, Martin and Grin, Juri and Tremel, Wolfgang
and Hermann, Raphael},
title = {{A} chemists view: {M}etal oxides with adaptive structures
for thermoelectric applications},
journal = {Physica status solidi / A},
volume = {213},
number = {3},
issn = {1862-6300},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2016-00824},
pages = {808–823},
year = {2016},
abstract = {Thermoelectric devices can help to tackle future challenges
in the energy sector through the conversion of waste heat
directly into usable electric energy. For a wide
applicability low-cost materials with reasonable
thermoelectric performances and cost-efficient preparation
techniques are required. In this context metal oxides are an
interesting class of materials because of their inherent
high-temperature stability and relative high sustainability.
Their thermoelectric performance, however, needs to be
improved for wide application. Compounds with adaptive
structures are a very interesting class of materials. A
slight reduction of early transition metal oxides generates
electrons as charge carriers and crystallographic shear
planes as structure motif. The crystallographic shear planes
lead to a reduction of intrinsic thermal conductivity. At
the same time, the electronic transport properties can be
tuned by the degree of reduction. So far only a few
transition metal oxides with adaptive structures have been
investigated with respect to their thermoelectric
properties, leaving much room for improvement. This review
gives an overview of thermoelectric oxides, highlights the
structural aspects of the crystallographic shear planes and
the resulting thermoelectric properties.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 524 -
Controlling Collective States (POF3-524) / 6212 - Quantum
Condensed Matter: Magnetism, Superconductivity (POF3-621) /
6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000372719800033},
doi = {10.1002/pssa.201532702},
url = {https://juser.fz-juelich.de/record/281119},
}