Journal Article

FZJ-2016-01657

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Electrostatic Effects on the Internal Dynamics of Redox-Sensitive Microgel Systems

Maccarrone, S. (Corresponding author)FZJ* ; Mergel, O. ; Plamper, F. A. ; Holderer, O.FZJ* ; Richter, D.FZJ*

2016
Soc. Washington, DC

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Please use a persistent id in citations: doi:10.1021/acs.macromol.5b02544

Abstract: Microgels are flexible entities with a number of properties which can be tailored for a variety of applications. For redox-sensitive PNIPAM-based microgels involved in this study, the size and effective charge of microgels can be manipulated by electrochemical means. The electrochemical switching is implemented via interaction of redox-sensitive counterions (hexacyanoferrates: HCF) with oppositely charged (cationic) thermoresponsive microgels. Effects on the internal dynamics upon uptake of HCF and increased hydrophobicity with temperature are investigated with neutron spin echo spectroscopy. The polymer segmental dynamics is well described by the Zimm model. Unbalanced charges (in absence of HCF) apparently shorten the polymer length acting like confined discontinuity points (pinning). This effect vanishes in the presence of HCF. The ability of multivalent ferricyanides to bind several monovalent polymer charges at the same time produces an apparent secondary network. This effective bridging makes the dynamics slower analogous to an increase in cross-linker density. In support of this picture, an enhanced viscosity of the medium, where the polymer chains move, was obtained by the fitting

Keyword(s): Polymers, Soft Nano Particles and Proteins (1st) ; Soft Condensed Matter (2nd)

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Contributing Institute(s):

1. JCNS-FRM-II (JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II)
2. Neutronenstreuung (Neutronenstreuung ; JCNS-1)

Research Program(s):

1. 6215 - Soft Matter, Health and Life Sciences (POF3-621) (POF3-621)
2. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)
3. 6G15 - FRM II / MLZ (POF3-6G15) (POF3-6G15)

Experiment(s):

1. J-NSE: Neutron spin-echo spectrometer (NL2ao)

Appears in the scientific report 2016

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Database coverage:
; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; No Authors Fulltext ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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