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@ARTICLE{Xie:283396,
      author       = {Xie, Jie and Harks, Peter-Paul R. M. L. and Li, Dongjiang
                      and Raijmakers, Lucas H. J. and Notten, Peter H. L.},
      title        = {{P}lanar and 3{D} deposition of {L}i4{T}i5{O}12 thin film
                      electrodes by {MOCVD}},
      journal      = {Solid state ionics},
      volume       = {287},
      issn         = {0167-2738},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2016-01790},
      pages        = {83 - 88},
      year         = {2016},
      abstract     = {Li4Ti5O12 is well known to be a safe and efficient anode
                      material for Li-ion batteries. A metal–organic chemical
                      vapor deposition process has been developed for the
                      synthesis of Li4Ti5O12 thin film anodes on planar and 3D
                      substrates. The influences of various deposition parameters,
                      including precursor flow rates and post-annealing
                      temperatures, have been investigated by material and
                      electrochemical analyses. Li4Ti5O12 thin films deposited at
                      the optimized process parameters showed a high crystallinity
                      and high electrochemical activity. A reversible storage
                      capacity of 151 mAh/g was achieved at a current of 0.5 C,
                      corresponding to $86.3\%$ of the theoretical specific
                      capacity of Li4Ti5O12. Up to almost 600 cycles, the
                      electrodes showed no significant capacity loss. Furthermore,
                      the deposited thin film anodes also showed excellent rate
                      performance. Compared to the storage capacity at 0.5 C,
                      $93\%$ of the capacity was maintained at 10 C. Thin films
                      were also deposited on highly structured substrates to
                      investigate the uniformity and electrochemical performance.
                      With the same footprint area, the 3D Li4Ti5O12 film anode
                      showed a 2.5 times higher storage capacity than planar
                      electrode.},
      cin          = {IEK-9},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000374199200013},
      doi          = {10.1016/j.ssi.2016.02.004},
      url          = {https://juser.fz-juelich.de/record/283396},
}