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000029426 084__ $$2WoS$$aEngineering, Electrical & Electronic
000029426 084__ $$2WoS$$aPhysics, Applied
000029426 084__ $$2WoS$$aPhysics, Condensed Matter
000029426 1001_ $$0P:(DE-Juel1)VDB2799$$aSzot, K.$$b0$$uFZJ
000029426 245__ $$aSegregation phenomena in thin films of BaTio3
000029426 260__ $$aLondon [u.a.]$$bTaylor & Francis$$c2001
000029426 300__ $$a303 -310
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000029426 440_0 $$02659$$aIntegrated Ferroelectrics$$v33$$x1058-4587
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000029426 520__ $$aThe near-surface region in perovskite bulk crystals is known to be subject to segregation processes at elevated temperatures which can lead to the formation of non-perovskite phases. We have addressed the question whether analogue phenomena may occur in thin films, Thin films of BaTiO3 prepared by different methods (PLD, CSD) and heat-treated in the temperature range of 700 degreesC-1000 degreesC are characterised by surface analytical methods and microanalysis (AFM, SIMS, XPS). Our studies reveals dramatic changes in the surface morphology and in-depth elemental distribution suggesting a chemical restructuring comparable to the effects known for single crystalline BaTiO3. Possible driving forces for the observed segregation phenomena are discussed taking into account specific properties of the thin films.
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000029426 65320 $$2Author$$athin films
000029426 65320 $$2Author$$asurface layer
000029426 65320 $$2Author$$asurface segregation
000029426 65320 $$2Author$$asurface morphology
000029426 65320 $$2Author$$aatomic force microscopy
000029426 7001_ $$0P:(DE-Juel1)VDB630$$aHoffmann, S.$$b1$$uFZJ
000029426 7001_ $$0P:(DE-Juel1)125382$$aSpeier, W.$$b2$$uFZJ
000029426 7001_ $$0P:(DE-Juel1)VDB2782$$aBreuer, U.$$b3$$uFZJ
000029426 7001_ $$0P:(DE-Juel1)VDB2542$$aSiegert, M.$$b4$$uFZJ
000029426 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b5$$uFZJ
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