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@ARTICLE{Karl:36214,
author = {Karl, M. and Brauers, T. and Dorn, H.-P. and Holland, F.
and Komenda, M. and Poppe, D. and Rohrer, F. and Rupp, L.
and Schaub, A. and Wahner, A.},
title = {{K}inetic study of the {OH}-isoprene and {O}3-isoprene
reaction in the atmosphere simulation chamber, {SAPHIR}},
journal = {Geophysical research letters},
volume = {31},
issn = {0094-8276},
address = {Washington, DC},
publisher = {American Geophysical Union},
reportid = {PreJuSER-36214},
pages = {1 - 4},
year = {2004},
note = {Record converted from VDB: 12.11.2012},
abstract = {Kinetic studies conducted in the new atmosphere simulation
chamber SAPHIR at the Research Center Julich allow a
thorough investigation of oxidation of isoprene induced by
O-3 and the OH radical under atmospheric conditions. Rate
coefficients for the O-3-isoprene and OH-isoprene reaction
are determined from measured concentration-time profiles.
For the reaction of O-3 with isoprene the rate coefficient
is determined to be (9.6 +/- 0.7) x 10(-18) cm(3)
molecule(-1) s(-1) at 286 K. The rate coefficient for the
reaction OH + isoprene is (10.0 +/- 1.2) x 10(-11) cm(3)
molecule(-1) s(-1) at 294 K. The kinetic parameters
determined in SAPHIR at atmospheric concentrations agree
well with recent recommendations.},
keywords = {J (WoSType)},
cin = {ICG-II},
ddc = {550},
cid = {I:(DE-Juel1)VDB48},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Geosciences, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000220432700003},
doi = {10.1029/2003GL019189},
url = {https://juser.fz-juelich.de/record/36214},
}