Home > Publications database > Kinetic study of the OH-isoprene and O3-isoprene reaction in the atmosphere simulation chamber, SAPHIR |
Journal Article | PreJuSER-36214 |
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2004
American Geophysical Union
Washington, DC
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Please use a persistent id in citations: http://hdl.handle.net/2128/7641 doi:10.1029/2003GL019189
Abstract: Kinetic studies conducted in the new atmosphere simulation chamber SAPHIR at the Research Center Julich allow a thorough investigation of oxidation of isoprene induced by O-3 and the OH radical under atmospheric conditions. Rate coefficients for the O-3-isoprene and OH-isoprene reaction are determined from measured concentration-time profiles. For the reaction of O-3 with isoprene the rate coefficient is determined to be (9.6 +/- 0.7) x 10(-18) cm(3) molecule(-1) s(-1) at 286 K. The rate coefficient for the reaction OH + isoprene is (10.0 +/- 1.2) x 10(-11) cm(3) molecule(-1) s(-1) at 294 K. The kinetic parameters determined in SAPHIR at atmospheric concentrations agree well with recent recommendations.
Keyword(s): J
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