TY - JOUR AU - Costina, I. AU - Franchy, R. TI - The band-gap of amorphous and well-ordered Al2O3 on Ni3Al(100) JO - Applied physics letters VL - 78 SN - 0003-6951 CY - Melville, NY PB - American Institute of Physics M1 - PreJuSER-39770 SP - 4139 PY - 2001 N1 - Record converted from VDB: 12.11.2012 AB - The vibrational and electronic properties of amorphous and well-ordered alumina formed on Ni3Al(100) were investigated using high-resolution electron energy loss spectroscopy. The structure of well-ordered alumina was analyzed by low-energy electron diffraction. The amorphous Al2O3 films are prepared by adsorption of O-2 at room temperature, while the well-ordered Al2O3 are obtained by direct oxidation of Ni3Al at 1150 K. The band gap energy is similar to3.2 and similar to4.3 eV for amorphous alumina and well-ordered alumina thin films respectively. The lowering of the band gap with respect to the bulk value of Al2O3 is associated with defect-induced states located in the band gap. (C) 2001 American Institute of Physics. KW - J (WoSType) LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000169340000026 DO - DOI:10.1063/1.1380403 UR - https://juser.fz-juelich.de/record/39770 ER -