Journal Article PreJuSER-39776

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Study of the water/poly(ethylene glycol) interface by IR-visible sum frequency generation

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2001
Elsevier Amsterdam [u.a.]

Chemical physics letters 333, 327 () [10.1016/S0009-2614(00)01383-X]

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Abstract: We used infrared-visible sum-frequency generation spectroscopy to investigate the vibrational properties of the water/poly(ethylene glycol) interface in the 2800-3800 cm(-1) spectral range. The vibrational fingerprint of the interface differs significantly from the one associated with the air/poly(ethylene glycol) interface. It is shown that the poly(ethylene glycol) molecular arrangement, originally relatively well-ordered, becomes disorganised in the presence of water. Moreover, a new OH band is identified demonstrating the strong interaction of water with the polymer. (C) 2001 Elsevier Science B.V. All rights reserved.

Keyword(s): J


Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Institut für Grenzflächen und Vakuumtechnologien (ISG-3)
Research Program(s):
  1. Struktur und Dynamik von Grenzflächen (29.25.0)

Appears in the scientific report 2001
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