Home > Publications database > Experimental absolute step and kink formation energies on Pb(111) vicinal surfaces |
Journal Article | PreJuSER-39838 |
; ;
2001
Elsevier
Amsterdam
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Please use a persistent id in citations: doi:10.1016/S0039-6028(01)01614-4
Abstract: Three-dimensional crystallites of Pb, equilibrated at various temperatures and imaged by scanning tunneling microscopy at temperature, have provided the basis for a quantitative determination of absolute step free energies and kink formation energies of vicinal Pb(l 11) surfaces. The anisotropy of large (111) facets was evaluated as a function of temperature. Products of radius times local curvature for A and B-steps of these facets were calculated and their dependence on temperature fitted by theoretical expressions. Absolute values of step energies at 0 K are f(1A) (0) = 131 meV and f(1B)(0) = 117 meV, with the corresponding kink energies Of epsilon(kA) = 40.0 meV and epsilon(kB) = 60.3 meV. (C) 2001 Elsevier Science B.V. All rights reserved.
Keyword(s): J ; equilibrium thermodynamics and statistical mechanics (auto) ; faceting (auto) ; surface energy (auto) ; scanning tunneling microscopy (auto) ; lead (auto) ; vicinal single crystal surfaces (auto)
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