Journal Article

PreJuSER-40327

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Contribution to the structural elucidation of 10 isomers of technical p-nonylphenol

Thiele, B.FZJ* ; Heinke, V.FZJ* ; Kleist, E.FZJ* ; Guenther, K.

2004
American Chemical Society Columbus, Ohio

This record in other databases:    

Please use a persistent id in citations: doi:10.1021/es040026g

Abstract: Gas chromatography-mass spectrometry (GC-MS) with a 100 m capillary column at different oven temperatures is employed to separate isothermally p-nonylphenol into 21 isomers. Analysis of the resulting mass spectra of these isomers indicates that they could be classified into six groups with respect to different configurations of the alpha- and beta-C-atoms on the alkyl chains. Based on these basic structures nonylphenol isomers are synthesized and also characterized by GC-MS. The obtained data elucidate the complete structures of 10 nonylphenol isomers of the technical mixture. The most important features of the mass spectra and the H-1 and C-13 nuclear magnetic resonance (NMR) spectra of these isomers are presented.

Keyword(s): J

Note: Record converted from VDB: 12.11.2012

---

Contributing Institute(s):

1. Phytosphäre (ICG-III)

Research Program(s):

1. Chemie und Dynamik der Geo-Biosphäre (U01)

Appears in the scientific report 2004

---

Database coverage:
JCR ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

---