TY  - JOUR
AU  - Thiele, B.
AU  - Heinke, V.
AU  - Kleist, E.
AU  - Guenther, K.
TI  - Contribution to the structural elucidation of 10 isomers of technical p-nonylphenol
JO  - Environmental Science & Technology
VL  - 38
SN  - 0013-936X
CY  - Columbus, Ohio
PB  - American Chemical Society
M1  - PreJuSER-40327
SP  - 3405 - 3411
PY  - 2004
N1  - Record converted from VDB: 12.11.2012
AB  - Gas chromatography-mass spectrometry (GC-MS) with a 100 m capillary column at different oven temperatures is employed to separate isothermally p-nonylphenol into 21 isomers. Analysis of the resulting mass spectra of these isomers indicates that they could be classified into six groups with respect to different configurations of the alpha- and beta-C-atoms on the alkyl chains. Based on these basic structures nonylphenol isomers are synthesized and also characterized by GC-MS. The obtained data elucidate the complete structures of 10 nonylphenol isomers of the technical mixture. The most important features of the mass spectra and the H-1 and C-13 nuclear magnetic resonance (NMR) spectra of these isomers are presented.
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000222051400037
DO  - DOI:10.1021/es040026g
UR  - https://juser.fz-juelich.de/record/40327
ER  -