Home > Publications database > Stable carbon isotope composition of secondary organic aerosol from ß-pinene oxidation > print

001     4242
005     20240712100948.0
024 7 _ |a 10.1029/2008JD011326
|2 DOI
024 7 _ |a WOS:000262749100003
|2 WOS
024 7 _ |a 0141-8637
|2 ISSN
024 7 _ |a 2128/20414
|2 Handle
037 _ _ |a PreJuSER-4242
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Meteorology & Atmospheric Sciences
100 1 _ |a Fisseha, R.
|b 0
|u FZJ
|0 P:(DE-Juel1)VDB66615
245 _ _ |a Stable carbon isotope composition of secondary organic aerosol from ß-pinene oxidation
260 _ _ |c 2009
|a Washington, DC
|b Union
300 _ _ |a D02304
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Geophysical Research D: Atmospheres
|x 0148-0227
|0 6393
|v 114
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a A chamber study was carried out to investigate the stable carbon isotopic composition (delta C-13) of secondary organic aerosol (SOA) formed from ozonolysis of beta-pinene. beta-Pinene (600 ppb) with a known delta C-13 value (-30.1%) and 500 ppb ozone were injected into the chamber in the absence of light and the resulting SOA was collected on preheated quartz fiber filters. Furthermore, delta C-13 values of the gas-phase beta-pinene and one of its oxidation products, nopinone, were measured using a gas chromatograph coupled to an isotope ratio mass spectrometer (GC-IRMS). beta-Pinene was progressively enriched with the heavy carbon isotope due to the kinetic isotope effect (KIE). The KIE of the reaction of beta-pinene with ozone was measured to be 1.0026 ((O3)epsilon 2.6 +/- 1.5 parts per thousand). The delta C-13 value of total secondary organic aerosol was very similar to that of its precursor (average = -29.6 +/- 0.2 parts per thousand) independent of experiment time. Nopinone, one of the major oxidation products of beta-pinene, was found in both the gas and aerosol phases. The gas-phase nopinone was heavier than the initial beta-pinene by 1.3 parts per thousand but lighter than the corresponding aerosol-phase nopinone. On average, the gas-phase nopinone was lighter by 2.3 parts per thousand than the corresponding aerosol- phase nopinone. The second product found in the SOA was detected as acetone, but it desorbed from the filter at a higher temperature than nopinone, which indicates that it is a pyrolysis product. The acetone showed a much lower delta C-13 (-36.6%) compared to the initial beta-pinene delta C-13.
536 _ _ |a Atmosphäre und Klima
|c P22
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK406
|x 0
536 _ _ |a Terrestrische Umwelt
|c P24
|0 G:(DE-Juel1)FUEK407
|x 1
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
|2 WoSType
700 1 _ |a Spahn, H.
|b 1
|u FZJ
|0 P:(DE-Juel1)VDB65140
700 1 _ |a Wegener, R.
|b 2
|u FZJ
|0 P:(DE-Juel1)2367
700 1 _ |a Hohaus, T.
|b 3
|u FZJ
|0 P:(DE-Juel1)VDB67355
700 1 _ |a Brasse, G.
|b 4
|u FZJ
|0 P:(DE-Juel1)VDB73213
700 1 _ |a Wissel, H.
|b 5
|u FZJ
|0 P:(DE-Juel1)VDB50316
700 1 _ |a Tillmann, R.
|b 6
|u FZJ
|0 P:(DE-Juel1)5344
700 1 _ |a Wahner, A.
|b 7
|u FZJ
|0 P:(DE-Juel1)16324
700 1 _ |a Koppmann, R.
|b 8
|0 P:(DE-HGF)0
700 1 _ |a Kiendler-Scharr, A.
|b 9
|u FZJ
|0 P:(DE-Juel1)4528
773 _ _ |0 PERI:(DE-600)2016800-7
|a 10.1029/2008JD011326
|g Vol. 114, p. D02304
|p D02304
|q 114|t Journal of Geophysical Research
|v 114
|x 0148-0227
|y 2009
|t Journal of geophysical research / Atmospheres
856 7 _ |u http://dx.doi.org/10.1029/2008JD011326
856 4 _ |u https://juser.fz-juelich.de/record/4242/files/2008JD011326.pdf
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/4242/files/2008JD011326.pdf?subformat=pdfa
|x pdfa
|y OpenAccess
909 C O |o oai:juser.fz-juelich.de:4242
|p openaire
|p open_access
|p VDB
|p driver
|p dnbdelivery
913 1 _ |k P22
|v Atmosphäre und Klima
|l Atmosphäre und Klima
|b Umwelt
|z fortgesetzt als P23
|0 G:(DE-Juel1)FUEK406
|x 0
913 1 _ |k P24
|v Terrestrische Umwelt
|l Terrestrische Umwelt
|b Erde und Umwelt
|0 G:(DE-Juel1)FUEK407
|x 1
914 1 _ |y 2009
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a JCR/ISI refereed
|0 StatID:(DE-HGF)0010
|2 StatID
915 _ _ |a Peer review
|0 StatID:(DE-HGF)0030
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Thomson Reuters Master Journal List
920 1 _ |d 30.09.2010
|g ICG
|k ICG-2
|l Troposphäre
|0 I:(DE-Juel1)VDB791
|x 1
920 1 _ |d 31.10.2010
|g ICG
|k ICG-4
|l Agrosphäre
|0 I:(DE-Juel1)VDB793
|x 2
920 1 _ |0 I:(DE-82)080012_20140620
|k JARA-HPC
|l Jülich Aachen Research Alliance - High-Performance Computing
|g JARA
|x 3
970 _ _ |a VDB:(DE-Juel1)110992
980 1 _ |a FullTexts
980 _ _ |a VDB
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)IEK-8-20101013
980 _ _ |a I:(DE-Juel1)IBG-3-20101118
980 _ _ |a I:(DE-82)080012_20140620
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)ICE-3-20101013
981 _ _ |a I:(DE-Juel1)IEK-8-20101013
981 _ _ |a I:(DE-Juel1)IBG-3-20101118
981 _ _ |a I:(DE-Juel1)VDB1346

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21