001     47396
005     20200423204229.0
017 _ _ |a This version is available at the following Publisher URL: http://jap.aip.org
024 7 _ |a 10.1063/1.1873033
|2 DOI
024 7 _ |a WOS:000228287300032
|2 WOS
024 7 _ |a 2128/1008
|2 Handle
037 _ _ |a PreJuSER-47396
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Physics, Applied
100 1 _ |a Regnery, S.
|b 0
|u FZJ
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245 _ _ |a SrTa2O6 thin films for high-K dielectric applications grown by chemical vapor deposition on different substrates
260 _ _ |a Melville, NY
|b American Institute of Physics
|c 2005
300 _ _ |a 073521
336 7 _ |a Journal Article
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440 _ 0 |a Journal of Applied Physics
|x 0021-8979
|0 3051
|v 97
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a SrTa2O6 thin films with thickness between 6 and 150 nm were deposited by metal-organic chemical vapor deposition in a multiwafer planetary reactor. The monomolecular precursor, strontium-tantalum-(methoxyethoxy)-ethoxide, was dissolved in toluene and injected by a liquid delivery system. A rather narrow process window for the deposition of stoichiometric SrTa2O6 was found for this precursor at low pressures and a susceptor temperature around 500 degrees C. Films were grown on Pt/TiO2/SiO2/Si, TiNx/Si, and SiO2/Si substrates. The as-deposited films were x-ray amorphous and could be crystallized by postannealing at a temperature >= 700 degrees C. The distorted tetragonal tungsten bronze phase of SrTa2O6 was dominating within a broad range of compositions (Sr/Ta: 0.4-0.7) and a perovskite-type phase was additionally observed for Sr/Ta>0.7 and predominated for Sr/Ta>1. The electrical properties have been investigated with metal-insulator-metal and metal-insulator-semiconductor capacitors after sputter deposition of Pt top electrodes. The amorphous films had a dielectric constant K in the range of 35-45 and low leakage currents. For stoichiometric SrTa2O6 the dielectric permittivity reached values of K=100-110, but the leakage currents were increased. Remarkably, the permittivity is not very sensitive to deviations from the exact stoichiometry of the SrTa2O6 phase (Sr/Ta: 0.4-0.7), but a decrease to values of K=30-40 is observed along with the transition to the perovskite phase at high Sr contents. (C) 2005 American Institute of Physics.
536 _ _ |a Materialien, Prozesse und Bauelemente für die Mikro- und Nanoelektronik
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700 1 _ |a Thomas, R.
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700 1 _ |a Ehrhart, P.
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700 1 _ |a Waser, R.
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773 _ _ |a 10.1063/1.1873033
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856 7 _ |u http://dx.doi.org/10.1063/1.1873033
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