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000051259 084__ $$2WoS$$aMineralogy
000051259 1001_ $$0P:(DE-HGF)0$$aPernyeszi, T.$$b0
000051259 245__ $$aOrganoclays for soil remediation: Adsorption of 2,4-dichlorophenol on organoclay/aquifer material mixtures studied under static and flow conditions
000051259 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2006
000051259 300__ $$a179 - 189
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000051259 440_0 $$0540$$aApplied Clay Science$$v32$$x0169-1317
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000051259 520__ $$aA column material containing organophilic clay particles was developed for soil remediation. 2,4-dichlorophenol adsorption on aquifer material with an effective particle diameter d<1 mm and various partially modified dioctadecyldimethylammoniummontmorillonite/aquifer material mixtures were studied under static and flow conditions. The 2,4-dichlorophenol adsorption on the aquifer material was negligible. On organoclay/aquifer material mixtures the adsorption capacity increased with increasing organoclay content and the adsorption isotherms could be fitted by the Freundlich equation. In columns filled with organoclay/ aquifer material mixtures, the 2,4-dichlorophenol retardation increased with increasing organoclay content up to 1% (w/w). Above 1.5-2.0% (w/w) the permeability of the column material decreased. The HYDRUS_1D model, which solves the convection-dispersion equation for solute transport, was used in a forward and inverse mode to simulate 2,4-dichlorophenol breakthrough in the columns. The simulations revealed that 2,4-dichlorophenol transport exhibited an additional kinetic effect not observed in the batch experiments. (C) 2006 Elsevier B.V. All rights reserved.
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000051259 65320 $$2Author$$aorganoclay
000051259 65320 $$2Author$$achlorophenol
000051259 65320 $$2Author$$aadsorption
000051259 65320 $$2Author$$acolumn technique
000051259 65320 $$2Author$$anumerical modelling
000051259 65320 $$2Author$$areactive barrier
000051259 7001_ $$0P:(DE-Juel1)VDB724$$aKasteel, R.$$b1$$uFZJ
000051259 7001_ $$0P:(DE-Juel1)VDB1799$$aWitthuhn, B.$$b2$$uFZJ
000051259 7001_ $$0P:(DE-Juel1)VDB4003$$aKlahre, P.$$b3$$uFZJ
000051259 7001_ $$0P:(DE-Juel1)129549$$aVereecken, H.$$b4$$uFZJ
000051259 7001_ $$0P:(DE-Juel1)129484$$aKlumpp, E.$$b5$$uFZJ
000051259 773__ $$0PERI:(DE-600)1492353-1$$a10.1016/j.clay.2006.01.004$$gVol. 32, p. 179 - 189$$p179 - 189$$q32<179 - 189$$tApplied clay science$$v32$$x0169-1317$$y2006
000051259 8567_ $$uhttp://dx.doi.org/10.1016/j.clay.2006.01.004
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