Home > Publications database > Organoclays for soil remediation: Adsorption of 2,4-dichlorophenol on organoclay/aquifer material mixtures studied under static and flow conditions |
Journal Article | PreJuSER-51259 |
; ; ; ; ;
2006
Elsevier
New York, NY [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.clay.2006.01.004
Abstract: A column material containing organophilic clay particles was developed for soil remediation. 2,4-dichlorophenol adsorption on aquifer material with an effective particle diameter d<1 mm and various partially modified dioctadecyldimethylammoniummontmorillonite/aquifer material mixtures were studied under static and flow conditions. The 2,4-dichlorophenol adsorption on the aquifer material was negligible. On organoclay/aquifer material mixtures the adsorption capacity increased with increasing organoclay content and the adsorption isotherms could be fitted by the Freundlich equation. In columns filled with organoclay/ aquifer material mixtures, the 2,4-dichlorophenol retardation increased with increasing organoclay content up to 1% (w/w). Above 1.5-2.0% (w/w) the permeability of the column material decreased. The HYDRUS_1D model, which solves the convection-dispersion equation for solute transport, was used in a forward and inverse mode to simulate 2,4-dichlorophenol breakthrough in the columns. The simulations revealed that 2,4-dichlorophenol transport exhibited an additional kinetic effect not observed in the batch experiments. (C) 2006 Elsevier B.V. All rights reserved.
Keyword(s): J ; organoclay (auto) ; chlorophenol (auto) ; adsorption (auto) ; column technique (auto) ; numerical modelling (auto) ; reactive barrier (auto)
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