Journal Article PreJuSER-51259

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Organoclays for soil remediation: Adsorption of 2,4-dichlorophenol on organoclay/aquifer material mixtures studied under static and flow conditions

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2006
Elsevier New York, NY [u.a.]

Applied clay science 32, 179 - 189 () [10.1016/j.clay.2006.01.004]

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Abstract: A column material containing organophilic clay particles was developed for soil remediation. 2,4-dichlorophenol adsorption on aquifer material with an effective particle diameter d<1 mm and various partially modified dioctadecyldimethylammoniummontmorillonite/aquifer material mixtures were studied under static and flow conditions. The 2,4-dichlorophenol adsorption on the aquifer material was negligible. On organoclay/aquifer material mixtures the adsorption capacity increased with increasing organoclay content and the adsorption isotherms could be fitted by the Freundlich equation. In columns filled with organoclay/ aquifer material mixtures, the 2,4-dichlorophenol retardation increased with increasing organoclay content up to 1% (w/w). Above 1.5-2.0% (w/w) the permeability of the column material decreased. The HYDRUS_1D model, which solves the convection-dispersion equation for solute transport, was used in a forward and inverse mode to simulate 2,4-dichlorophenol breakthrough in the columns. The simulations revealed that 2,4-dichlorophenol transport exhibited an additional kinetic effect not observed in the batch experiments. (C) 2006 Elsevier B.V. All rights reserved.

Keyword(s): J ; organoclay (auto) ; chlorophenol (auto) ; adsorption (auto) ; column technique (auto) ; numerical modelling (auto) ; reactive barrier (auto)

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Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Agrosphäre (ICG-IV)
  2. Jülich-Aachen Research Alliance - Energy (JARA-ENERGY)
Research Program(s):
  1. Terrestrische Umwelt (P24)

Appears in the scientific report 2006
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 Record created 2012-11-13, last modified 2018-02-11



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