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@ARTICLE{Pernyeszi:51259,
author = {Pernyeszi, T. and Kasteel, R. and Witthuhn, B. and Klahre,
P. and Vereecken, H. and Klumpp, E.},
title = {{O}rganoclays for soil remediation: {A}dsorption of
2,4-dichlorophenol on organoclay/aquifer material mixtures
studied under static and flow conditions},
journal = {Applied clay science},
volume = {32},
issn = {0169-1317},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-51259},
pages = {179 - 189},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {A column material containing organophilic clay particles
was developed for soil remediation. 2,4-dichlorophenol
adsorption on aquifer material with an effective particle
diameter d<1 mm and various partially modified
dioctadecyldimethylammoniummontmorillonite/aquifer material
mixtures were studied under static and flow conditions. The
2,4-dichlorophenol adsorption on the aquifer material was
negligible. On organoclay/aquifer material mixtures the
adsorption capacity increased with increasing organoclay
content and the adsorption isotherms could be fitted by the
Freundlich equation. In columns filled with organoclay/
aquifer material mixtures, the 2,4-dichlorophenol
retardation increased with increasing organoclay content up
to $1\%$ (w/w). Above $1.5-2.0\%$ (w/w) the permeability of
the column material decreased. The $HYDRUS_1D$ model, which
solves the convection-dispersion equation for solute
transport, was used in a forward and inverse mode to
simulate 2,4-dichlorophenol breakthrough in the columns. The
simulations revealed that 2,4-dichlorophenol transport
exhibited an additional kinetic effect not observed in the
batch experiments. (C) 2006 Elsevier B.V. All rights
reserved.},
keywords = {J (WoSType)},
cin = {ICG-IV / JARA-ENERGY},
ddc = {550},
cid = {I:(DE-Juel1)VDB50 / $I:(DE-82)080011_20140620$},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Mineralogy},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000238134000003},
doi = {10.1016/j.clay.2006.01.004},
url = {https://juser.fz-juelich.de/record/51259},
}