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@ARTICLE{Stadler:5171,
      author       = {Stadler, A.M. and Embs, J.P. and Digel, I. and Artmann,
                      G.M. and Unruh, T. and Büldt, G. and Zaccai, G.},
      title        = {{C}ytoplasmic {W}ater and {H}ydration {L}ayer {D}ynamics in
                      {H}uman {R}ed {B}lood {C}ells},
      journal      = {Journal of the American Chemical Society},
      volume       = {130},
      number       = {50},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PreJuSER-5171},
      pages        = {16852 - 16853},
      year         = {2008},
      note         = {We thank Franz Dernmel for help with the experiment on
                      IRIS, Aysegul Temiz Artmann and Dariusz Porst for help
                      during sample preparation, and Moeava Tehei and Marion
                      Jasnin for fruitful discussions. This work is based on
                      experiments performed at the neutron sources SINQ FRM II and
                      ISIS. This research project has been supported by the
                      European Commission under the sixth Framework Programme
                      through the Key Action: Strengthening the European Research
                      Area, Research Infrastructures. Contract No:
                      RII3-CT-2003-505925.},
      abstract     = {The dynamics of water in human red blood cells was measured
                      with quasielastic incoherent neutron scattering in the
                      temperature range between 290 and 320 K. Neutron
                      spectrometers with time resolutions of 40, 13, and 7 ps were
                      combined to cover time scales of bulk water dynamics to
                      reduced mobility interfacial water motions. A major fraction
                      of approximately $90\%$ of cell water is characterized by a
                      translational diffusion coefficient similar to bulk water. A
                      minor fraction of approximately $10\%$ of cellular water
                      exhibits reduced dynamics. This slow water fraction was
                      attributed to dynamically bound water on the surface of
                      hemoglobin which accounts for approximately half of the
                      hydration layer.},
      keywords     = {Cytoplasm: chemistry / Erythrocytes: chemistry / Humans /
                      Water: chemistry / Water (NLM Chemicals) / J (WoSType)},
      cin          = {ISB-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ISB-2-20090406},
      pnm          = {Programm Biosoft},
      pid          = {G:(DE-Juel1)FUEK443},
      experiment   = {EXP:(DE-MLZ)TOF-TOF-20140101},
      shelfmark    = {Chemistry, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:19053467},
      UT           = {WOS:000263320400014},
      doi          = {10.1021/ja807691j},
      url          = {https://juser.fz-juelich.de/record/5171},
}