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024 7 _ |2 DOI
|a 10.1007/s10008-005-0090-y
024 7 _ |2 WOS
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037 _ _ |a PreJuSER-53200
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Electrochemistry
100 1 _ |a Munoz, A. G.
|b 0
|u FZJ
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245 _ _ |a Electrodeposition of Metals on Anodized Thin Nb Films
260 _ _ |a Berlin
|b Springer
|c 2006
300 _ _ |a 329 - 336
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |a Journal of Solid State Electrochemistry
|x 1432-8488
|0 12701
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|v 10
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The influence of the electronic properties of oxidized Nb surfaces on the electrodeposition of metals (Me=Co, Cu, Ag) with different equilibrium potentials U-Me/Mez studied by conventional electrochemical techniques and atomic force microscopy. The results show that relatively thin anodic Nb2O5 films (thickness < 11 nm) present a frequency-dependent n-type semiconductor behavior, which can be described by the theory of amorphous semiconductor. The Schottky barrier, formed at the a-Nb2O5/electrolyte interface, affects the deposition rate of metals with equilibrium potentials more positive than the flat band potential (UMe/Mez+ > U-FB). Then, the dependence of density of states on the oxide thickness and anodization conditions leads to different extents of the band bending, affecting directly the rate of electron transfer.
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653 2 0 |2 Author
|a Nb oxide
653 2 0 |2 Author
|a electrodeposition
653 2 0 |2 Author
|a n-semiconductors
700 1 _ |a Staikov, G.
|b 1
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|0 P:(DE-Juel1)VDB13645
773 _ _ |a 10.1007/s10008-005-0090-y
|g Vol. 10, p. 329 - 336
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|t Journal of solid state electrochemistry
|v 10
|y 2006
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856 7 _ |u http://dx.doi.org/10.1007/s10008-005-0090-y
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914 1 _ |y 2006
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k ISG-3
|l Institut für Grenzflächen und Vakuumtechnologien
|d 31.12.2006
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|l Center of Nanoelectronic Systems for Information Technology
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