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| 084 | _ | _ | |2 WoS |a Electrochemistry |
| 100 | 1 | _ | |a Munoz, A. G. |b 0 |u FZJ |0 P:(DE-Juel1)VDB60931 |
| 245 | _ | _ | |a Electrodeposition of Metals on Anodized Thin Nb Films |
| 260 | _ | _ | |a Berlin |b Springer |c 2006 |
| 300 | _ | _ | |a 329 - 336 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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| 440 | _ | 0 | |a Journal of Solid State Electrochemistry |x 1432-8488 |0 12701 |y 5 |v 10 |
| 500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
| 520 | _ | _ | |a The influence of the electronic properties of oxidized Nb surfaces on the electrodeposition of metals (Me=Co, Cu, Ag) with different equilibrium potentials U-Me/Mez studied by conventional electrochemical techniques and atomic force microscopy. The results show that relatively thin anodic Nb2O5 films (thickness < 11 nm) present a frequency-dependent n-type semiconductor behavior, which can be described by the theory of amorphous semiconductor. The Schottky barrier, formed at the a-Nb2O5/electrolyte interface, affects the deposition rate of metals with equilibrium potentials more positive than the flat band potential (UMe/Mez+ > U-FB). Then, the dependence of density of states on the oxide thickness and anodization conditions leads to different extents of the band bending, affecting directly the rate of electron transfer. |
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| 653 | 2 | 0 | |2 Author |a Nb oxide |
| 653 | 2 | 0 | |2 Author |a electrodeposition |
| 653 | 2 | 0 | |2 Author |a n-semiconductors |
| 700 | 1 | _ | |a Staikov, G. |b 1 |u FZJ |0 P:(DE-Juel1)VDB13645 |
| 773 | _ | _ | |a 10.1007/s10008-005-0090-y |g Vol. 10, p. 329 - 336 |p 329 - 336 |q 10<329 - 336 |0 PERI:(DE-600)1478940-1 |t Journal of solid state electrochemistry |v 10 |y 2006 |x 1432-8488 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1007/s10008-005-0090-y |
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| 915 | _ | _ | |0 StatID:(DE-HGF)0010 |a JCR/ISI refereed |
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