Journal Article

PreJuSER-53214

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Reply to: "Remarks on the Simulation of Cl Electrosorption on Au(100) reported in Electrochimica Acta 50 (2005) 5518

Rikvold, P. A. ; Wandlowski, T.FZJ* ; Hamad, I. A. ; Michell, S. J. ; Brown, G.

2007
Elsevier New York, NY [u.a.]

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Please use a persistent id in citations: doi:10.1016/j.electacta.2006.07.059

Abstract: We reply to the remarks by Lang and Horanyi [G.G. Lang, G. Horanyi, Electrochim. Acta (2006), doi: 10.1016/j.electacta.2006.07.009] on the meaning of the notion of "electrosorption valency" used by Abou Hamad et al. [I. Abou Hamad, S.J. Mitchell, Th. Wandlowski, P.A. Rikvold, G. Brown, Electrochim. Acta 50 (2005) 5518]. It is concluded that, contrary to the assertion of Lang and Horanyi, the magnitude of the current in the external circuit upon adsorption of an ion of charge ze with partial charge transfer is indeed given by an electrosorption valency gamma such that vertical bar ye vertical bar < vertical bar ze vertical bar. We believe the conclusion of Lang and Horanyi to the contrary is the result of an excessively severe charge-neutrality requirement. (c) 2006 Elsevier B.V. All rights reserved.

Keyword(s): J ; electrosorption (auto) ; electrosorption valency (auto) ; formal partial charge number (auto) ; lateral interactions (auto) ; surface dipole (auto)

Note: Record converted from VDB: 12.11.2012

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Contributing Institute(s):

1. Grenz- und Oberflächen (IBN-3)
2. Center of Nanoelectronic Systems for Information Technology (CNI)
3. Jülich-Aachen Research Alliance - Fundamentals of Future Information Technology (JARA-FIT)

Research Program(s):

1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2007

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