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@ARTICLE{Schneller:58030,
author = {Schneller, T. and Waser, R.},
title = {{C}hemical modifications of {P}b({Z}r0.3,{T}i0.7){O}3
precursor solutions and their influence on the morphological
and electrical properties of the resulting thin films},
journal = {Journal of sol gel science and technology},
volume = {42},
issn = {0928-0707},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {PreJuSER-58030},
pages = {337 - 352},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {Tetragonal lead zirconate titanate thin films on platinized
silicon wafers have been prepared from chemically different
precursor solutions by chemical solution deposition.
Literature known routes have been evaluated and an optimized
standard process has been developed leading to
Pb(Zr-0.3,Ti-0.7)O-3 films with a high degree of (111)
orientation which consequently shows square hysteris loops
with Pr values of 34 mu C/cm(2).Other solvents, different
alkoxides of the transition metals, and different
carboxylates of lead have been systematically introduced in
this standard process and their influence on the final
morphological and electrical properties has been studied. It
has been found that the use of lead (II) propionate and
titanium tetra n-butoxide for solution synthesis leads to a
decrease of the remanent polarization of similar to $50\%.$
Furthermore the reaction atmosphere after spinning and
during the pyrolysis has been investigated. Increased
ambient humidity after the spin coating process also caused
a significant deterioration of the final film properties.
The findings have been explained in terms of a hindered
formation of the (111) texture promoting intermediate PtxPb
phase.},
keywords = {J (WoSType)},
cin = {IFF-6 / CNI / JARA-FIT},
ddc = {600},
cid = {I:(DE-Juel1)VDB786 / I:(DE-Juel1)VDB381 /
$I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien /
Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK412 / G:(DE-Juel1)FUEK414},
shelfmark = {Materials Science, Ceramics},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000245899500022},
doi = {10.1007/s10971-007-0764-2},
url = {https://juser.fz-juelich.de/record/58030},
}