Journal Article

PreJuSER-6233

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Aerosol Mass Spectrometric Features of Biogenic SOA: Observations from a Plant Chamber and in Rural Atmospheric Environments

Kiendler-Scharr, A.FZJ* ; Zhang, Q. ; Hohaus, T.FZJ* ; Kleist, E.FZJ* ; Mensah, A.FZJ* ; Mentel, T. F.FZJ* ; Spindler, C.FZJ* ; Uerlings, R.FZJ* ; Tillmann, R.FZJ* ; Wildt, J.FZJ*

2009
American Chemical Society Columbus, Ohio

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Please use a persistent id in citations: doi:10.1021/es901420b

Abstract: Secondary organic aerosol (SOA) is known to form from a variety of anthropogenic and biogenic precursors. Current estimates of global SOA production vary over 2 orders of magnitude. Since no direct measurement technique for SOA exists, quantifying SOA remains a challenge for atmospheric studies. The identification of biogenic SOA (BSOA) based on mass spectral signatures offers the possibility to derive source information of organic aerosol (OA) with high time resolution. Here we present data from simulation experiments. The BSOA from tree emissions was characterized with an Aerodyne quadrupole aerosol mass spectrometer (Q-AMS). Collection efficiencies were close to 1, and effective densities of the BSOA were found to be 1.3 +/- 0.1 g/cm(3). The mass spectra of SOA from different trees were found to be highly similar. The average BSOA mass spectrum from tree emissions is compared to a BSOA component spectrum extracted from field data. It is shown that overall the spectra agree well and that the mass spectral features of BSOA are distinctively different from those of OA components related to fresh fossil fuel and biomass combustions. The simulation chamber mass spectrum may potentially be useful for the identification and interpretation of biogenic SOA components in ambient data sets.

Keyword(s): Aerosols: analysis (MeSH) ; Atmosphere: chemistry (MeSH) ; Mass Spectrometry (MeSH) ; Organic Chemicals: analysis (MeSH) ; Particle Size (MeSH) ; Time Factors (MeSH) ; Trees: chemistry (MeSH) ; Volatilization (MeSH) ; Aerosols ; Organic Chemicals ; J

Note: We gratefully acknowledge support by the European Commission (IP-EUCAARI, Contract No. 036833-2). Q.Z. was supported by the U.S. Department of Energy's Atmospheric Science Program (Office of Science, BER), Grant No. DE-FG02-08ER64627. We thank James Allan (U. Manchester) for the AMS data analysis software and anonymous reviewers for their constructive comments.

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Research Program(s):

1. Atmosphäre und Klima (P22)
2. Terrestrische Umwelt (P24)

Appears in the scientific report 2009

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Database coverage:
; JCR ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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