| Home > Publications database > Experimental Determination of the Thermodynamic Properties of the Laves Phases in the Cr–Fe–Nb System |
| Journal Article | FZJ-2016-02302 |
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2016
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.tca.2015.12.001
Abstract: Standard enthalpies of formation, ΔfH, of the Laves-phases within their solid solutions along the Cr2Nb–Fe2Nb section were measured using drop solution calorimetry for the first time. The enthalpy values change linearly from −2.9 kJ mol−1 atom−1 for binary C15-Cr2Nb to −13.6 kJ mol−1 atom−1 for C14-Fe2Nb. The obtained values are compared with some earlier results on the binary compounds gathered mostly from ab initio calculations.
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