000810170 001__ 810170 000810170 005__ 20240711085638.0 000810170 0247_ $$2doi$$a10.1007/s11666-016-0383-y 000810170 0247_ $$2ISSN$$a1059-9630 000810170 0247_ $$2ISSN$$a1544-1016 000810170 0247_ $$2WOS$$aWOS:000374328500003 000810170 037__ $$aFZJ-2016-03045 000810170 082__ $$a670 000810170 1001_ $$0P:(DE-Juel1)159408$$aMarcano, D.$$b0$$eCorresponding author 000810170 245__ $$aThe Role of Oxygen Partial Pressure in Controlling the Phase Composition of La$_{1−x}$ Sr $_{x}$ Co $_{y}$ Fe$_{1−y}$ O$_{3−δ}$ Oxygen Transport Membranes Manufactured by Means of Plasma Spray-Physical Vapor Deposition 000810170 260__ $$aBoston, Mass.$$bSpringer$$c2016 000810170 3367_ $$2DRIVER$$aarticle 000810170 3367_ $$2DataCite$$aOutput Types/Journal article 000810170 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1493183481_1224 000810170 3367_ $$2BibTeX$$aARTICLE 000810170 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000810170 3367_ $$00$$2EndNote$$aJournal Article 000810170 520__ $$aLa0.58Sr0.4Co0.2Fe0.8O3− δ (LSCF) deposited on a metallic porous support by plasma spray-physical vapor deposition is a promising candidate for oxygen-permeation membranes. Ionic transport properties are regarded to depend on the fraction of perovskite phase present in the membrane. However, during processing, the LSCF powder decomposes into perovskite and secondary phases. In order to improve the ionic transport properties of the membranes, spraying was carried out at different oxygen partial pressures p(O2). It was found that coatings deposited at lower and higher oxygen partial pressures consist of 70% cubic/26% rhombohedral and 61% cubic/35% rhombohedral perovskite phases, respectively. During annealing, the formation of non-perovskite phases is driven by oxygen non-stoichiometry. The amount of oxygen added during spraying can be used to increase the perovskite phase fraction and suppress the formation of non-perovskite phases 000810170 536__ $$0G:(DE-HGF)POF3-113$$a113 - Methods and Concepts for Material Development (POF3-113)$$cPOF3-113$$fPOF III$$x0 000810170 588__ $$aDataset connected to CrossRef 000810170 7001_ $$0P:(DE-Juel1)129633$$aMauer, G.$$b1 000810170 7001_ $$0P:(DE-Juel1)159368$$aSohn, Y. J.$$b2 000810170 7001_ $$0P:(DE-Juel1)129670$$aVassen, Robert$$b3$$ufzj 000810170 7001_ $$0P:(DE-HGF)0$$aGarcia-Fayos, J.$$b4 000810170 7001_ $$0P:(DE-HGF)0$$aSerra, J. 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