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@ARTICLE{Esat:819515,
author = {Esat, Taner and Lechtenberg, Benedikt and Deilmann,
Thorsten and Wagner, Christian and Krüger, Peter and
Temirov, Ruslan and Rohlfing, Michael and Anders, Frithjof
B. and Tautz, F. S.},
title = {{A} chemically driven quantum phase transition in a
two-molecule {K}ondo system},
journal = {Nature physics},
volume = {12},
number = {9},
issn = {1745-2481},
address = {Basingstoke},
publisher = {Nature Publishing Group},
reportid = {FZJ-2016-05158},
pages = {867 - 873},
year = {2016},
abstract = {The magnetic properties of nanostructures that consist of a
small number of atoms or molecules are typically determined
by magnetic exchange interactions. Here, we show that
non-magnetic, chemical interactions can have a similarly
decisive effect if spin-moment-carrying orbitals extend in
space and therefore allow the direct coupling of magnetic
properties to wavefunction overlap and the formation of
bonding and antibonding orbitals. We demonstrate this for a
dimer of metal–molecule complexes on the Au(111) surface.
A changing wavefunction overlap between the two monomers
drives the surface-adsorbed dimer through a quantum phase
transition from an underscreened triplet to a singlet ground
state, with one configuration being located extremely close
to a quantum critical point.},
cin = {PGI-3 / NIC},
ddc = {530},
cid = {I:(DE-Juel1)PGI-3-20110106 / I:(DE-Juel1)NIC-20090406},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143) /
Nonequilibrium dynamics of quantum impurity systems close
quantum phase transitions $(hhb00_20130501)$ / Spectra of 2D
layered materials $(hms17_20140501)$},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143 /
$G:(DE-Juel1)hhb00_20130501$ / $G:(DE-Juel1)hms17_20140501$},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000383219800015},
doi = {10.1038/nphys3737},
url = {https://juser.fz-juelich.de/record/819515},
}