Home > Publications database > Lissodendrins A and B: 2-Aminoimidazole Alkaloids from the Marine Sponge Lissodendoryx (Acanthodoryx) fibrosa |
Journal Article | FZJ-2016-05392 |
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2016
Wiley-VCH Verl.
Weinheim
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Please use a persistent id in citations: doi:10.1002/ejoc.201501250
Abstract: Chemical investigation of the Indonesian sponge Lissodendoryx (Acanthodoryx) fibrosa yielded the new 2-aminoimidazole alkaloids lissodendrins A (1) and B (2). Their structures were unambiguously determined by extensive NMR spectroscopic (1H, 13C, ROESY and long-range HMBC) studies and mass spectrometric (HRESIMS/MS) data. Lissodendrins A (1) and B (2) possess unprecedented skeletons with the latter compound bearing a (p-hydroxyphenyl)glyoxal moiety, which is rarely encountered in natural products. A plausible biosynthetic pathway for these new metabolites is proposed.
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