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100 1 _ |a Schulz, Margot
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245 _ _ |a Benzoxazolinone detoxification by N-Glucosylation: The multi-compartment-network of Zea mays L.
260 _ _ |a Austin, Tex.
|c 2016
|b Landes Bioscience
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520 _ _ |a The major detoxification product in maize roots after 24 h benzoxazolin-2(3H)-one (BOA) exposure was identified as glucoside carbamate resulting from rearrangement of BOA-N-glucoside, but the pathway of N-glucosylation, enzymes involved and the site of synthesis were previously unknown. Assaying whole cell proteins revealed the necessity of H2O2 and Fe2+ ions for glucoside carbamate production. Peroxidase produced BOA radicals are apparently formed within the extraplastic space of the young maize root. Radicals seem to be the preferred substrate for N-glucosylation, either by direct reaction with glucose or, more likely, the N-glucoside is released by glucanase/glucosidase catalyzed hydrolysis from cell wall components harboring fixed BOA. [...]
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700 1 _ |a Filary, Barbara
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700 1 _ |a Kühn, Sabine
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700 1 _ |a Colby, Thomas
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700 1 _ |a Harzen, Anne
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700 1 _ |a Schmidt, Jürgen
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700 1 _ |a Sicker, Dieter
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700 1 _ |a Hennig, Lothar
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700 1 _ |a Hofmann, Diana
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700 1 _ |a Disko, Ulrich
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700 1 _ |a Anders, Nico
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773 _ _ |a 10.1080/15592324.2015.1119962
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