Journal Article

FZJ-2016-05446

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Benzoxazolinone detoxification by N-Glucosylation: The multi-compartment-network of Zea mays L.

Schulz, M. (Corresponding author) ; Filary, B. ; Kühn, S. ; Colby, T. ; Harzen, A. ; Schmidt, J. ; Sicker, D. ; Hennig, L. ; Hofmann, D.FZJ* ; Disko, U. ; Anders, N.

2016
Landes Bioscience Austin, Tex.

This record in other databases:      

Please use a persistent id in citations: doi:10.1080/15592324.2015.1119962

Abstract: The major detoxification product in maize roots after 24 h benzoxazolin-2(3H)-one (BOA) exposure was identified as glucoside carbamate resulting from rearrangement of BOA-N-glucoside, but the pathway of N-glucosylation, enzymes involved and the site of synthesis were previously unknown. Assaying whole cell proteins revealed the necessity of H2O2 and Fe2+ ions for glucoside carbamate production. Peroxidase produced BOA radicals are apparently formed within the extraplastic space of the young maize root. Radicals seem to be the preferred substrate for N-glucosylation, either by direct reaction with glucose or, more likely, the N-glucoside is released by glucanase/glucosidase catalyzed hydrolysis from cell wall components harboring fixed BOA. [...]

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Contributing Institute(s):

1. Agrosphäre (IBG-3)

Research Program(s):

1. 255 - Terrestrial Systems: From Observation to Prediction (POF3-255) (POF3-255)

Appears in the scientific report 2016

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Database coverage:
; Emerging Sources Citation Index ; NCBI Molecular Biology Database ; No Authors Fulltext ; SCOPUS ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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