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@ARTICLE{Redhammer:820545,
author = {Redhammer, G. J. and Rettenwander, D. and Pristat, S. and
Dashjav, E. and Kumar, C. M. N. and Topa, D. and Tietz, F.},
title = {{A} single crystal {X}-ray and powder neutron diffraction
study on {NASICON}-type
{L}i$_{1+x}${A}l$_{x}${T}i$_{2−x}$({PO}$_{4}$)$_{3}$
(0 ≤ x ≤ 0.5) crystals: {I}mplications on ionic
conductivity},
journal = {Solid state sciences},
volume = {60},
issn = {1293-2558},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2016-05827},
pages = {99 - 107},
year = {2016},
abstract = {Single crystals of NASICON-type material
Li1+xTi2−xAlx(PO4)3 (LATP) with 0 ≤ x ≤ 0.5 were
successfully grown using long-term sintering techniques.
Sample material was studied by chemical analysis, single
crystal X-ray and neutron diffraction. The Ti4+ replacement
scales very well with the Al3+ and Li+ incorporation. The
additional Li+ thereby enters the M3 cavity of the NASICON
framework at x, y, z ∼ (0.07, 0.34, 0.09) and is regarded
to be responsible for the enhanced Li+ conduction of LATP as
compared to Al-free LTP. Variations in structural
parameters, associated with the Ti4+ substitution with Al3+
+ Li+ will be discussed in detail in this paper.},
cin = {IEK-1 / JCNS-SNS / IEK-12},
ddc = {550},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)JCNS-SNS-20110128
/ I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000384779800014},
doi = {10.1016/j.solidstatesciences.2016.08.011},
url = {https://juser.fz-juelich.de/record/820545},
}