% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Redhammer:820545, author = {Redhammer, G. J. and Rettenwander, D. and Pristat, S. and Dashjav, E. and Kumar, C. M. N. and Topa, D. and Tietz, F.}, title = {{A} single crystal {X}-ray and powder neutron diffraction study on {NASICON}-type {L}i$_{1+x}${A}l$_{x}${T}i$_{2−x}$({PO}$_{4}$)$_{3}$ (0 ≤ x ≤ 0.5) crystals: {I}mplications on ionic conductivity}, journal = {Solid state sciences}, volume = {60}, issn = {1293-2558}, address = {Amsterdam [u.a.]}, publisher = {Elsevier}, reportid = {FZJ-2016-05827}, pages = {99 - 107}, year = {2016}, abstract = {Single crystals of NASICON-type material Li1+xTi2−xAlx(PO4)3 (LATP) with 0 ≤ x ≤ 0.5 were successfully grown using long-term sintering techniques. Sample material was studied by chemical analysis, single crystal X-ray and neutron diffraction. The Ti4+ replacement scales very well with the Al3+ and Li+ incorporation. The additional Li+ thereby enters the M3 cavity of the NASICON framework at x, y, z ∼ (0.07, 0.34, 0.09) and is regarded to be responsible for the enhanced Li+ conduction of LATP as compared to Al-free LTP. Variations in structural parameters, associated with the Ti4+ substitution with Al3+ + Li+ will be discussed in detail in this paper.}, cin = {IEK-1 / JCNS-SNS / IEK-12}, ddc = {550}, cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)JCNS-SNS-20110128 / I:(DE-Juel1)IEK-12-20141217}, pnm = {131 - Electrochemical Storage (POF3-131)}, pid = {G:(DE-HGF)POF3-131}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000384779800014}, doi = {10.1016/j.solidstatesciences.2016.08.011}, url = {https://juser.fz-juelich.de/record/820545}, }