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@ARTICLE{Markus:824669,
author = {Markus, Isaac M. and Prill, Marco and Dang, Siaufung and
Markus, Torsten and Spatschek, Robert and Singheiser,
Lorenz},
title = {{H}igh {T}emperature {I}nvestigation of {E}lectrochemical
{L}ithium {I}nsertion {I}nto {L}i$_{4}${T}i$_{5}${O}$_{12}$},
journal = {Physical chemistry, chemical physics},
volume = {18},
number = {46},
issn = {1463-9084},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2016-07227},
pages = {31640 - 31644},
year = {2016},
abstract = {Li4Ti5O12 was synthesized via a solid state reaction and
lithiated at 400 °C in a custom built galvanostatic cell
consisting of a molten LiCl–KCl electrolyte and Li-Al
alloy wires as counter and reference electrodes. The
material exhibits decreased rate capability at 400 °C
compared to the room temperature behavior. Electrochemical
lithiation at C/20 exhibits a discharge profile with both a
sloping curve and flat plateau, which is indicative of a
solid solution behavior before reaching a two phase region.
This electrochemical behavior is shown to be correlated with
reversible formation of the cubic Li2TiO3 phase.},
cin = {IEK-2},
ddc = {540},
cid = {I:(DE-Juel1)IEK-2-20101013},
pnm = {111 - Efficient and Flexible Power Plants (POF3-111) /
HITEC - Helmholtz Interdisciplinary Doctoral Training in
Energy and Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-111 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000389333700029},
doi = {10.1039/C6CP05466H},
url = {https://juser.fz-juelich.de/record/824669},
}