| Home > Publications database > High Temperature Investigation of Electrochemical Lithium Insertion Into Li$_{4}$Ti$_{5}$O$_{12}$ |
| Journal Article | FZJ-2016-07227 |
; ; ; ; ;
2016
RSC Publ.
Cambridge
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Please use a persistent id in citations: doi:10.1039/C6CP05466H
Abstract: Li4Ti5O12 was synthesized via a solid state reaction and lithiated at 400 °C in a custom built galvanostatic cell consisting of a molten LiCl–KCl electrolyte and Li-Al alloy wires as counter and reference electrodes. The material exhibits decreased rate capability at 400 °C compared to the room temperature behavior. Electrochemical lithiation at C/20 exhibits a discharge profile with both a sloping curve and flat plateau, which is indicative of a solid solution behavior before reaching a two phase region. This electrochemical behavior is shown to be correlated with reversible formation of the cubic Li2TiO3 phase.
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