Journal Article FZJ-2016-07227

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High Temperature Investigation of Electrochemical Lithium Insertion Into Li$_{4}$Ti$_{5}$O$_{12}$

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2016
RSC Publ. Cambridge

Physical chemistry, chemical physics 18(46), 31640 - 31644 () [10.1039/C6CP05466H]

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Abstract: Li4Ti5O12 was synthesized via a solid state reaction and lithiated at 400 °C in a custom built galvanostatic cell consisting of a molten LiCl–KCl electrolyte and Li-Al alloy wires as counter and reference electrodes. The material exhibits decreased rate capability at 400 °C compared to the room temperature behavior. Electrochemical lithiation at C/20 exhibits a discharge profile with both a sloping curve and flat plateau, which is indicative of a solid solution behavior before reaching a two phase region. This electrochemical behavior is shown to be correlated with reversible formation of the cubic Li2TiO3 phase.

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Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
Research Program(s):
  1. 111 - Efficient and Flexible Power Plants (POF3-111) (POF3-111)
  2. HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) (HITEC-20170406)

Appears in the scientific report 2016
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Medline ; Allianz-Lizenz / DFG ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; No Authors Fulltext ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2016-12-08, last modified 2024-07-09



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