%0 Journal Article
%A Izarova, Natalya V.
%A Santiago-Schübel, Beatrix
%A Willbold, Sabine
%A Hess, Volkmar
%A Kögerler, Paul
%T Classical/Non-classical Polyoxometalate Hybrids
%J Chemistry - a European journal
%V 22
%N 45
%@ 0947-6539
%C Weinheim
%I Wiley-VCH
%M FZJ-2016-07566
%P 16052 - 16056
%D 2016
%X Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000387132800011
%$ pmid:27617918
%R 10.1002/chem.201604238
%U https://juser.fz-juelich.de/record/825086