Journal Article

FZJ-2016-07566

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Classical/Non-classical Polyoxometalate Hybrids

Izarova, N. V. (Corresponding author)FZJ* ; Santiago-Schübel, B.FZJ* ; Willbold, S.FZJ* ; Hess, V.FZJ* ; Kögerler, P.FZJ*

2016
Wiley-VCH Weinheim

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Please use a persistent id in citations: http://hdl.handle.net/2128/13210  doi:10.1002/chem.201604238

Abstract: Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.

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Contributing Institute(s):

1. Analytik (ZEA-3)
2. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 899 - ohne Topic (POF3-899) (POF3-899)

Appears in the scientific report 2016

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Database coverage:
; ; ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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