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000825086 1001_ $$0P:(DE-Juel1)157892$$aIzarova, Natalya V.$$b0$$eCorresponding author
000825086 245__ $$aClassical/Non-classical Polyoxometalate Hybrids
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000825086 520__ $$aTwo polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
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000825086 7001_ $$0P:(DE-Juel1)133853$$aSantiago-Schübel, Beatrix$$b1
000825086 7001_ $$0P:(DE-Juel1)133857$$aWillbold, Sabine$$b2
000825086 7001_ $$0P:(DE-Juel1)156530$$aHess, Volkmar$$b3
000825086 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b4
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