TY  - JOUR
AU  - Izarova, Natalya V.
AU  - Santiago-Schübel, Beatrix
AU  - Willbold, Sabine
AU  - Hess, Volkmar
AU  - Kögerler, Paul
TI  - Classical/Non-classical Polyoxometalate Hybrids
JO  - Chemistry - a European journal
VL  - 22
IS  - 45
SN  - 0947-6539
CY  - Weinheim
PB  - Wiley-VCH
M1  - FZJ-2016-07566
SP  - 16052 - 16056
PY  - 2016
AB  - Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000387132800011
C6  - pmid:27617918
DO  - DOI:10.1002/chem.201604238
UR  - https://juser.fz-juelich.de/record/825086
ER  -